1996 – 2000

Palladium-assisted formation of carbon-carbon bonds. 9. Synthesis of (2-alkenylaryl)- and indenylpalladium complexes

Vicente, J.; Abad, J. A.; Bergs, R.; de Arellano, M. C. R.; Martínez-Viviente, E.; Jones, P. G. Organometallics 2000, 19, 5597.

http://dx.doi.org/10.1021/om000370w

 

Syntheses, structure, and molecular cubic hyperpolarizabilities of systematically varied ethynylgold(I) complexes

Vicente, J.; Chicote, M. T.; Abrisqueta, M. D.; de Arellano, M. C. R.; Jones, P. G.; Humphrey, M. G.; Cifuentes, M. P.; Samoc, M.; Luther-Davies, B. Organometallics 2000, 19, 2968.

http://dx.doi.org/10.1021/om000093t

 

A novel type of alkynylgold(I) complex. Crystal and molecular structures of PPN Au(Ar)(C equivalent to CH) Ar = C6F5, C6H2(NO2)(3)-2,4,6

Vicente, J.; Chicote, M. T.; Abrisqueta, M. D.; Jones, P. G. Organometallics 2000, 19, 2629.

http://dx.doi.org/10.1021/om9910322

 

Synthesis of palladium complexes with ortho-functionalized aryl ligands

Vicente, J.; Abad, J. A.; Martínez-Viviente, E.; de Arellano, M. C. R.; Jones, P. G. Organometallics 2000, 19, 752.

http://dx.doi.org/10.1021/om9905963

 

Complexes with S-donor ligands. 7. New 1,1-ethylenedithiolato complexes of thallium(I), gold(I), and gold(III): Syntheses, structure, and molecular cubic hyperpolarizabilities

Vicente, J.; Chicote, M. T.; González-Herrero, P.; Jones, P. G.; Humphrey, M. G.; Cifuentes, M. P.; Samoc, M.; Luther-Davies, B. Inorg. Chem. 1999, 38, 5018.

http://dx.doi.org/10.1021/ic990379u

 

Synthesis and reactivity of 2-aminophenylpalladium(II) complexes: Insertion reactions of oxygen and carbon monoxide into carbon-palladium bonds – New examples of “transphobia”

Vicente, J.; Abad, J. A.; Frankland, A. D.; de Arellano, M. C. R. Chem. Eur. J. 1999, 5, 3066.

http://dx.doi.org/10.1002/(sici)1521-3765(19991001)5:10<3066::aid-chem3066>3.0.co;2-f

 

The ‘acac method’ for the synthesis of coordination and organometallic compounds: synthesis of gold complexes

Vicente, J.; Chicote, M. T. Coordination Chemistry Reviews 1999, 193-5, 1143.

http://dx.doi.org/10.1016/s0010-8545(99)00083-1

 

Synthesis of the first complex with acetonine as ligand: the first crystal structure of an acetonine derivative

Vicente, J.; Chicote, M. T.; Guerrero, R.; de Arellano, M. C. R. Chem. Commun. 1999, 1541.

http://dx.doi.org/10.1039/a904777h

 

Multidonor ligands. 3. Cyclopalladation of py{SCH2C(O)R}-2 (py-2=2-pyridyl, R = Ph, Me, OMe) through a C(sp(3))-H bond activation

Vicente, J.; Chicote, M. T.; Rubio, C.; de Arellano, M. C. R.; Jones, P. G. Organometallics 1999, 18, 2750.

http://dx.doi.org/10.1021/om981043f

 

Nucleophilic attack of carbonyl-stabilized phosphorus ylides on 1,5-cyclooctadiene complexes of palladium and platinum

Vicente, J.; Chicote, M. T.; MacBeath, C.; Fernández-Baeza, J.; Bautista, D. Organometallics 1999, 18, 2677.

http://dx.doi.org/10.1021/om9901022

 

Palladium-assisted formation of carbon-carbon bonds. 8. Synthesis and reactivity toward internal alkynes, carbon monoxide, and isocyanides of orthopalladated dibenzylamine complexes

Vicente, J.; Saura-Llamas, I.; Turpin, J.; de Arellano, M. C. R.; Jones, P. G. Organometallics 1999, 18, 2683.

http://dx.doi.org/10.1021/om990143y

 

Multidonor ligands. 2. Room-temperature C(sp(3))-H activation of 2-(alkylthio)pyridine by gold(III) complexes

Vicente, J.; Chicote, M. T.; Lozano, M. I.; Huertas, S. Organometallics 1999, 18, 753.

http://dx.doi.org/10.1021/om980747m

 

Gold(I) and palladium(II) complexes containing the functionalized ylides triarylphosphonium cyanomethylide or 2-cyanoethylide (R3P=CHR ‘, R ‘ = CN, CH2CN)

Vicente, J.; Chicote, M. T.; Lagunas, M. C. Helv. Chim. Acta 1999, 82, 1202.

http://dx.doi.org/10.1002/(sici)1522-2675(19990804)82:8<1202::aid-hlca1202>3.0.co;2-g

 

Attempts to prepare palladium(II) complexes with the O,C,O pincer aryl ligand C-6(NO2)(2)-2,6-(OMe)(3)-3,4,5

Vicente, J.; Arcas, A.; Blasco, M. A.; Lozano, J.; de Arellano, M. C. R. Organometallics 1998, 17, 5374.

http://dx.doi.org/10.1021/om980633a

 

Palladium(II) complexes of monoaryliminophosphorane derivatives of 1,2-bis(diphenylphosphino)methane. Crystal structure of Pd{kappa(2)-C6H3(N=N-C6H4Me-4 ‘)-2-(C6H4Me-4 ”)-5-C,N ‘}{kappa(2)-PPh2CH2P(=NC6H4Me-4)Ph-2-P,N}

Vicente, J.; Arcas, A.; Bautista, D.; de Arellano, M. C. R. Organometallics 1998, 17, 4544.

http://dx.doi.org/10.1021/om980445k

 

Synthesis of new ketonyl palladium(II) and platinum(II) complexes with nitrogen-donor ligands. Crystal structure of Pt{CH2C(O)Me}(2)(bpy)

Vicente, J.; Abad, J. A.; Chicote, M. T.; Abrisqueta, M. D.; Lorca, J. A.; de Arellano, M. C. R. Organometallics 1998, 17, 1564.

http://dx.doi.org/10.1021/om971028v

 

Multidonor ligands, 1 – Synthesis and structural characterization of gold(I) and silver(I) complexes of the multidonor ligand 2-(phenacylthio)pyridine – Crystal structures of (AuPPh3){py{SCH2C(O)Ph}-2} (ClO4) and (AgPPh3)(OClO3){py{SCH2C(O)Ph}-2}

Vicente, J.; Chicote, M. T.; Huertas, S.; de Arellano, M. C. R.; Jones, P. G. Eur. J. Inorg. Chem. 1998, 511.

 

Recent advances in the chemistry of gold(I) complexes with C-, N- and S-donor ligands part I: Alkynyl, amino, imino and nitrido derivatives

Vicente, J.; Chicote, M. T.; Abrisqueta, M. D.; González-Herrero, P.; Guerrero, R. Gold. Bull. 1998, 31, 83.

 

Recent advances in the chemistry of gold(I) complexes with C-, N- and S-donor ligands part II: Sulfur ylide, hydrosulfido, sulfido, trithiocarbonato, dithiocarbimato and 1,1-ethylenedithiolato derivatives

Vicente, J.; Chicote, M. T.; Abrisqueta, M. D.; González-Herrero, P.; Guerrero, R. Gold. Bull. 1998, 31, 126.

 

Transition metal complexes and precursors

Kukushkin, V. Y.; Oskarsson, A.; Elding, L. I.; Farrell, N.; Vicente, J.; Chicote, M. T.; Kauffman, G. B.; Houghten, R. A.; Likins, R. E.; Posson, P. L.; Ray, R. K.; Tkachuk, V. M.; Vorobiov-Desiatovsky, N. V.; Hill, G. S.; Irwin, M. J.; Levy, C. J.; Rendina, L. M.; Puddephatt, R. J.; Romeo, R.; Monsu’scolaro, L.; Ruffo, F.; De Renzi, A.; Panunzi, A.; Byers, P. K.; Canty, A. J.; Jin, H.; Kruis, D.; Markies, B. A.; Boersma, J.; van Koten, G.; Nazeeruddin, K.; Kalyanasundaram, R.; Gratzel, M.; Bessel, C. A.; Leising, R. A.; Szczepura, L. F.; Perez, W. J.; Huyhn, M. H. V.; Takeuchi, K. J.; Poli, R.; Krueger, S. T.; Mattamana, S. P.; Jacobsen, C. J. H.; Klinke, K. K.; Hyldtoft, J.; Villadsen, J.; Abernethy, C. D.; Botommley, F.; Chen, J.; Kemp, M. F.; Mallais, T. C.; Womiloju, O. O.; Morris, R. J.; Shaw, S. L.; Jefferis, J. M.; Storhoff, J. J.; Goedde, D. M.; Hakanson, M. Inorganic Syntheses 1998, 32, 141.

 

New neutral and anionic alkynylgold(I) complexes via new synthetic methods. Crystal and molecular structures of (PPh3)(2)N Au(C CCH2OH)(2) , Au(C CSiMe3)((CNBu)-Bu-t) , and Au(C CR)PR ‘(3) (R ‘ = cyclohexyl, R = CH2Cl, CH2Br; R ‘ = Ph, R = SiMe3, Bu-t)

Vicente, J.; Chicote, M. T.; Abrisqueta, M. D.; Jones, P. G. Organometallics 1997, 16, 5628.

http://dx.doi.org/10.1021/om970725k

 

Complexes with S-donor ligands. 6. Synthesis of the first family of (trithiocarbonato)gold complexes. Crystal structure of (PPh3)2N[AuCl2(CS3)]

Vicente, J.; Chicote, M. T.; González-Herrero, P.; Jones, P. G. Inorg. Chem. 1997, 36, 5735.

http://dx.doi.org/10.1021/ic970478c

 

Synthesis of mercury(II) and palladium(II) organometallic derivatives of terephthaldehyde by metalation, transmetalation, oxidation, and condensation reactions. X-ray crystal structures of trans- PdCl{C6H3(CO2H)(2)-2,5}(PPh3)(2) center dot Me2CO center dot 2MeOH, trans- PdCl{C6H3(CHO)-2-(CO2H)-5}(PPh3)(2) center dot 2CH(2)Cl(2), and Pd{C6H3(CH=NC6H4NH2-4)-2-(CHO)-5}(N,N,N’,N’-tetramethylethylenediamine) CF3SO3. Molecular assemblies through Pd -Cl center dot center dot center dot HO2C-aryl and Pd -Cl center dot center dot center dot HOMe HO(O)C-aryl hydrogen bonds

Vicente, J.; Abad, J. A.; Rink, B.; Hernández, F. S.; Ramírez de Arellano, M. C. Organometallics 1997, 16, 5269.

http://dx.doi.org/10.1021/om970583u

 

CS2 insertion into a gold-carbon bond. First syntheses and characterization of 2,2-diacetylethylene-1,1-dithiolato complexes. Crystal structure of N(PPh3)(2) Au{eta(2)-S2C=C(COMe)(2)}(2)

Vicente, J.; Chicote, M. T.; González-Herrero, P.; Jones, P. G. Chem. Commun. 1997, 2047.

http://dx.doi.org/10.1039/a705052f

 

Restricted rotation around the P-C bond in metalated phosphonium salts: A variable-temperature H-1 NMR study. X-ray crystal structures of {AuP(C6H11)(3)}(2){mu-C(PTo(3))(py-2)} ClO4 and (AuPPh3)(2){mu-{C(PPh3)(py-2)}(AuPPh3)} (CF3SO3)(2)

Vicente, J.; Chicote, M. T.; Lagunas, M. C.; Jones, P. G.; Ahrens, B. Inorg. Chem. 1997, 36, 4938.

http://dx.doi.org/10.1021/ic970367d

 

Palladium-assisted formation of carbon-carbon bonds .7. Reactions of (2,3,4-trimethoxy-6-X-phenyl)palladium complexes with alkynes (X=C(O)NHBut) and isocyanides (X=C(O)NHBut, C(O)Me, CHO): Crystal and molecular structures of Pd{C6H{C(O)NHBut}-6-(OMe)(3)-2,3,4}(bpy) (CF3SO3), Pd{C(CO2Me)=C(CO2Me)C6H{(C(O)NHBut}-6-(OMe)(3)-2,3,4)}-Cl(PPh3) , Pd{C(=NXy)C6H{C(O)NHBut}-6-(OMe)(3)-2,3,4}-(bpy) (CF3SO3), and the ketenimine 2-(2,6-dimethylphenyl)-1-(((2,6-dimethylphenyl)imino)-methylene)-5,6,7-t rimethoxy-3-oxoisoindoline

Vicente, J.; Abad, J. A.; Shaw, K. F.; Gil-Rubio, J.; Ramírez de Arellano, M. C. Organometallics 1997, 16, 4557.

http://dx.doi.org/10.1021/om970426v

 

Gold(I) complexes with N-donor ligands .2. Reactions of ammonium salts with Au(acac-kappa C-2)(PR3) to give Au(NH3)L (+), (AuL)(2)(mu(2)-NH2) (+), (AuL)(4)(mu(4)-N) (+), or (AuL)(3)(mu(3)-O) (+). A new and facile synthesis of Au(NH3)(2) (+) salts. Crystal structure of {AuP(C6H4OMe-4)(3)}(3)(mu(3)-O) CF3SO3

Vicente, J.; Chicote, M. T.; Guerrero, R.; Jones, P. G.; Ramírez de Arellano, M. C. Inorg. Chem. 1997, 36, 4438.

http://dx.doi.org/10.1021/ic970225j

 

Complexes with S-donor ligands .5. syntheses of the first (hydrosulfido)- and anionic sulfidoorganogold(I) complexes. Crystal and molecular structure of (Et4N)(2) {Au(C6F5)}(3)(mu(3)-S) center dot 0.5MeC(O)Et

Vicente, J.; Chicote, M. T.; González-Herrero, P.; Grünwald, C.; Jones, P. G. Organometallics 1997, 16, 3381.

http://dx.doi.org/10.1021/om970106b

 

New motifs in aurophilic self-assembly: Synthesis and structures of Au(NH=CMe2)(2) CF3SO3 and Au(C CSiMe3)(CNtBu)

Vicente, J.; Chicote, M. T.; Abrisqueta, M. D.; Guerrero, R.; Jones, P. G. Angew. Chem., Int. Ed. Engl. 1997, 36, 1203.

http://dx.doi.org/10.1002/anie.199712031

 

Room-temperature oxidation of 2-aminobenzoyl- to 2-aminobenzoato-palladium(II) complexes and of coordinated PPh3 by atmospheric oxygen; X-ray crystal structure of (PPh3)(2)Pd(NH2C6H4CO2-2)Pd{C(O)C6H4NH2-2}(PPh3) O3SCF3

Vicente, J.; Abad, J. A.; Frankland, A. D.; Ramírez de Arellano, M. C. Chem. Commun. 1997, 959.

http://dx.doi.org/10.1039/a701552f

 

The difficulty of coordinating mutually trans phosphine and aryl ligands in palladium complexes and its relation to important coupling processes. Syntheses and crystal structures of a family of palladium phosphino, triflato, perchlorato, and aquo-8-(arylazo)aryl complexes

Vicente, J.; Arcas, A.; Bautista, D.; Jones, P. G. Organometallics 1997, 16, 2127.

http://dx.doi.org/10.1021/om961094h

 

Orthometalation of primary amines .4. Orthopalladation of primary benzylamines and (2-phenylethyl)amine

Vicente, J.; SauraLlamas, I.; Palin, M. G.; Jones, P. G.; de Arellano, M. C. R. Organometallics 1997, 16, 826.

http://dx.doi.org/10.1021/om9609574

 

Synthesis and reactivity of some nitroaryl complexes of Hg-II and Au-III – Synthesis of a substituted biphenyl by C-C coupling – Crystal structure of Hg(C6H4NO2-3,OnBu-6)(2)

Vicente, J.; Bermúdez, M. D.; Carrión, F. J.; Jones, P. G. Chemische Berichte 1996, 129, 1395.

http://dx.doi.org/10.1002/cber.19961291114

 

Platinum-assisted addition of carbonyl-stabilized phosphorus ylides to pentafluorobenzonitrile and acetonitrile to give platinum(II) complexes containing iminophosphorane and/or N-bonded beta-imino phosphorus ylide ligands. Crystal and molecular structures of trans- PtCl2{E-NH=C(C6F5)C(=PPh(3))C(O)Me}(2) and trans- PtCl2{E-N(=PPh(3))C(C6F5)=CHCO(2)Et}{E-NH=C(C6F5)C(=PPh(3))CO(2)E t}

Vicente, J.; Chicote, M. T.; Beswick, M. A.; Ramírez de Arellano, M. C. Inorg. Chem. 1996, 35, 6592.

http://dx.doi.org/10.1021/ic951666a

 

Synthesis of mono-, di-, and tri-arylgold(III) complexes using organomercury compounds – Synthesis of the first aurated Schiff bases

Vicente, J.; Bermúdez, M. D.; Carrión, F. J.; Jones, P. G. Chemische Berichte 1996, 129, 1301.

http://dx.doi.org/10.1002/cber.19961291025

 

Palladium-assisted formation of carbon-carbon bonds .6. Study of the reactivity of (o-formylaryl)- or (o-acetylaryl)palladium complexes with alkynes. Synthesis of indenones and indenols

Vicente, J.; Abad, J. A.; Gil Rubio, J. Organometallics 1996, 15, 3509.

http://dx.doi.org/10.1021/om960203p

 

Palladium-assisted formation of carbon-carbon bonds .5. Reactions of (o-styrylaryl)palladium complexes with alkynes. Synthesis of palladium complexes with highly functionalized indenyl ligands. Crystal and molecular structures of (1-benzyl-2,3-diphenyl-5,6,7-trimethoxyindenyl)- and (1-benzyl-3-phenyl-5,6,7-trimethoxyindenyl)palladium(II) complexes

Vicente, J.; Abad, J. A.; Bergs, R.; Jones, P. G.; Ramírez de Arellano, M. C. Organometallics 1996, 15, 1422.

http://dx.doi.org/10.1021/om950847h

 

Complexes with S-donor ligands .4. Mono- and di-homo- and hetero-nuclear gold(I), silver(I), and palladium(II) complexes with 2-(methylthio)pyridine, pyridine-2(1H)-thione, and benzoxazole-2(3H)-thione. Some examples of the use of complexes as ligands

Vicente, J.; Chicote, M. T.; Rubio, C. Chemische Berichte 1996, 129, 327.

http://dx.doi.org/10.1002/cber.19961290313

 

Isolation of a postulated intermediate in the Stille reaction. Synthesis of 2-arylazoarylphosphonium salts via C-P coupling. Synthesis of acetone complexes of palladium(II). Crystal and molecular structure of Pd(C6H4N=NPh-2)(PPh(3))(acetone) , Ph(3)P{C6H3(N(2)C(6)H(4)Me-4′)-2-Me-5} ClO4 and Pd(O,O-acac)(PPh(3))(2) ClO4

Vicente, J.; Arcas, A.; Bautista, D.; Tiripicchio, A.; Camellini, M. T. New. J. Chem. 1996, 20, 345.

 

Synthesis of some mu-hydroxo-, phenoxo- and O,O-acetylacetonato-arylgold(III) complexes. Crystal structure of Au(C6H4NO2-2)(2)(mu-OH) (2)center dot 2Et(2)O

Vicente, J.; Bermúdez, M. D.; Carrion, F. J.; Jones, P. G. J. Organomet. Chem. 1996, 508, 53.

http://dx.doi.org/10.1016/0022-328x(95)05772-h

 

Synthesis of the first complex with a hypercoordinate ylidic carbon atom. Crystal and molecular structure of {Au(PPh(3))}4CS(=O)Me(2) (ClO4)(2)

Vicente, J.; Chicote, M. T.; Guerrero, R.; Jones, P. G. J. Am. Chem. Soc. 1996, 118, 699.

http://dx.doi.org/10.1021/ja953504j

 

Palladium-assisted formation of carbon-carbon bonds .4. Synthesis and reactivity of a water-soluble (2,3,4-trimethoxy-6-(ethoxymethyl)phenyl)palladium(II) complex. Reactions with alkynes of its derivatives: Further insight into the pathway of formation of highly functionalized organic spirocycles and X-ray structures of model intermediates

Vicente, J.; Abad, J. A.; Fernández de Bobadilla, R.; Jones, P. G.; Ramírez de Arellano, M. C. Organometallics 1996, 15, 24.

http://dx.doi.org/10.1021/om950603x