1991 – 1995

Platinum-Assisted C-C Bond Formation – Synthesis Of Platinum Imidoyl Phosphorus Ylide Complexes And The First Crystal-Structure Of An Imidoyl Phosphorus Ylide Complex

Vicente, J.; Chicote, M. T.; Lagunas, M. C.; Jones, P. G. Inorg. Chem. 1995, 34, 5441.

http://dx.doi.org/10.1021/ic00126a012

 

The First Ligand-Assisted Stereoselective Wittig Reactions – Synthesis And Crystal-Structure Of The 3-Palladaindan-1-One, Pd(C6h C(O)Ch2 -6-(Ome)(3)-2,3,4)(Me(2)Nch(2)Ch(2)Nme(2))

Vicente, J.; Abad, J. A.; Bergs, R.; Jones, P. G.; Bautista, D. J. Chem. Soc., Dalton Trans. 1995, 3093.

http://dx.doi.org/10.1039/dt9950003093

 

Orthometallated Primary Amines .2. Insertion Of Internal Acetylenes Into Orthopalladated Alpha-Methylbenzylamine – Crystal-Structure Of PD(C(PH)=C(PH)C(PH)=C(PH)C6H4CH(ME)NH2)BR

Vicente, J.; Saurallamas, I.; Ramírez de Arellano, M. C. J. Chem. Soc., Dalton Trans. 1995, 2529.

http://dx.doi.org/10.1039/dt9950002529

 

Orthometallated Primary Amines .3. The First Orthopalladation Of A Primary Nitrobenzylamine – Synthesis Of Chiral Cyclopalladated Complexes Derived From (S)-Alpha-Methyl-4-Nitrobenzylamine

Vicente, J.; Saura-Llamas, I.; Palin, M. G.; Jones, P. G. J. Chem. Soc., Dalton Trans. 1995, 2535.

http://dx.doi.org/10.1039/dt9950002535

 

Palladium-Assisted Formation Of Carbon-Carbon Bonds .3. Study Of Reactions Of Bis(Eta(2)-(2,3,4-Trimethoxy-6-Acetylphenyl-C,O))Bis(Mu-Chloro)Dipalladi Um(Ii) With Symmetrical And Unsymmetrical Internal Alkynes – A Stoichiometric Route To Highly Functionalized Spirocyclic And Benzofulvene Compounds – Isolation Of A Pi-Allylic Palladium Intermediate – X-Ray Structure Of 10-(1-Hydroxyethyl)-6,7-Dimethoxy-1,2,3,4-Tetraphenylspiro 4.5 1,3,6,9-D Ecatetraen-8-One

Vicente, J.; Abad, J. A.; Gil-Rubio, J. Organometallics 1995, 14, 2677.

http://dx.doi.org/10.1021/om00006a014

 

Gold(I) Complexes With N-Donor Ligands .1. Synthesis Of Complexes Au(Pph(3))L (+) (L=Primary, Secondary Or Tertiary Amine) – Crystal-Structure Of Au(Pph(3))(Nme(3)) Clo4 Center-Dot-Ch2cl2

Vicente, J.; Chicote, M. T.; Guerrero, R.; Jones, P. G. J. Chem. Soc., Dalton Trans. 1995, 1251.

http://dx.doi.org/10.1039/dt9950001251

 

Synthesis Of The First Trithiocarbonatogold Complex – N(Pph(3))(2) (2) Au-2(Mu(2)-Eta(2)-Cs3)(2) – First Crystal-Structure Of A Mu(2)-Eta(2)-Bridging Trithiocarbonato Complex

Vicente, J.; Chicote, M. T.; González-Herrero, P.; Jones, P. G. J. Chem. Soc., Chem. Commun. 1995, 745.

http://dx.doi.org/10.1039/c39950000745

 

Alkynyl Gold(I) Complexes – The First Family Of Ethynyl Gold(I) Complexes

Vicente, J.; Chicote, M. T.; Abrisqueta, M. D. J. Chem. Soc., Dalton Trans. 1995, 497.

http://dx.doi.org/10.1039/dt9950000497

 

Complexes With S-Donor Ligands .2. Synthesis Of Anionic Bis(Thiolato)Gold(I) Complexes – Crystal-Structure Of N(Pph3)2 Au(Sr)2 (R=Benzoxazol-2-Yl)

Vicente, J.; Chicote, M. T.; González-Herrero, P.; Jones, P. G. J. Chem. Soc., Dalton Trans. 1994, 3183.

http://dx.doi.org/10.1039/dt9940003183

 

The Use Of Thermotropic Liquid-Crystals In Organometallic Chemistry – Synthesis Of New Mercury, Silver And Gold Complexes With 4,4′-Disubstituted Azobenzenes

Vicente, J.; Bermúdez, M. D.; Carrión, F. J.; Martínez-Nicolás, G. J. Organomet. Chem. 1994, 480, 103.

http://dx.doi.org/10.1016/0022-328x(94)87107-8

 

A Postulated Carrier Of Gold In Hydrothermal Ore Solutions – Synthesis And Crystal-Structure Of (Ph(3)P)(2)N Au(Sh)(2) , The First Homoleptic Hydrogensulfido Complex

Vicente, J.; Chicote, M. T.; González-Herrero, P.; Jones, P. G.; Ahrens, B. Angew. Chem., Int. Ed. Engl. 1994, 33, 1852.

http://dx.doi.org/10.1002/anie.199418521

 

Palladium-Assisted Formation Of Carbon-Carbon Bonds .2. Stoichiometric Synthesis Of Spirocyclic Compounds – X-Ray Structure Of A Pi-Allylic Palladium Intermediate

Vicente, J.; Abad, J. A.; Gil-Rubio, J.; Jones, P. G. Inorganica Chimica Acta 1994, 222, 1.

http://dx.doi.org/10.1016/0020-1693(94)03889-9

 

Gold In Organic-Synthesis .2. Preparation Of Benzyl-Alkyl And Benzyl-Arylketones Via C-C Coupling

Vicente, J.; Bermúdez, M. D.; Carrión, F. J. Inorganica Chimica Acta 1994, 220, 1.

http://dx.doi.org/10.1016/0020-1693(94)03878-3

 

Aerobic Photooxidation And C-C Bond-Cleavage Of The Acetylacetonate Ligand In (2-Arylazo)Arylpalladium(II) Complexes Induced by Visible-Light

Vicente, J.; Arcas, A.; Bautista, D.; Shulpin, G. B. J. Chem. Soc., Dalton Trans. 1994, 1505.

http://dx.doi.org/10.1039/dt9940001505

 

Synthesis And Double C-H Activation Of Palladium(II) Complexes With the Cationic Ligand To3PCH2(Py-2)+ (To=C6H4Me-4, Py=Pyridine) – Some Evidence Of The Formation Of A Palladium(IV) Complex – Crystal And Molecular-Structures of trans-PdCl2(py(CH2PTo3)-2)2 (ClO4)2·CH2Cl2, PdCl(Mu(2)-Kappa(3)-C6H3(PTo2CH(Py-2′)-2)Me-4)2·CH2Cl2, and cis-PdI2(Kappa(2)-C6H3(PTo2CHCl(Py-2′)-2)Me-4)·CH2Cl2

Vicente, J.; Chicote, M. T.; Lagunas, M. C.; Jones, P. G.; Bembenek, E. Organometallics 1994, 13, 1243.

http://dx.doi.org/10.1021/om00016a029

 

SYNTHESIS OF YLIDES R3P=C(C6F4X-4)R’ AND PHOSPHONIUM SALTS R3PCH(C6F4X-4)R’ (+) (X=CN OR NO2) BY REACTING YLIDES R3P=CHR’ WITH C6F5X

Vicente, J.; Chicote, M. T.; Fernández-Baeza, J.; Fernández-Baeza, A. New. J. Chem. 1994, 18, 263.

 

Orthometallated Primary Amines.1. Facile Preparation Of The 1st Optically-Active Cyclopalladated Primary Amines

Vicente, J.; Saura-Llamas, I.; Jones, P. G. J. Chem. Soc., Dalton Trans. 1993, 3619.

http://dx.doi.org/10.1039/dt9930003619

 

(Diphenylphosphine)Gold(I), (Diphenylphosphido)Gold(I), And (Diphenylphosphinito)Gold(I) Complexes – Crystal-Structure Of (PPh3)2n Au(P(O)Ph2)2

Vicente, J.; Chicote, M. T.; Jones, P. G. Inorg. Chem. 1993, 32, 4960.

http://dx.doi.org/10.1021/ic00074a048

 

A New Example Of A Palladium-Assisted Aryl Rearrangement – Synthesis And Reactivity Of (2,3,4-Trimethoxy-6-X-Phenyl)Palladium X=Cho, Ch=N(N-C10h21), Ch=Nc6h4(Nh2)-2,C(0)Me And (3,4,5-Trimethoxy-2-X-Phenyl)Palladium X=Cho,Ch=Nc6h4(Nh2)-2 Complexes – Crystal And Molecular-Structure Of Pd(Kappa(3)-C6h(Ch=Nc6h4(Nh2)2)-6-(Ome)3-2,3,4)(Pph3) Cf3so3, Pd(Kappa(3)-C6h(Ch=Nc6h4(Nh2)-2)-2-(Ome)3-3,4,5)(Pph3) Cf3so3, And Pd(Kappa(2)-C6h(C(0)Me)-6-(Ome)3-2,3,4)(2,9-Dimethyl-1,10-Phenanthrolin E) Cf3so3

Vicente, J.; Abad, J. A.; Gil-Rubio, J.; Jones, P. G.; Bembenek, E. Organometallics 1993, 12, 4151.

http://dx.doi.org/10.1021/om00034a059

 

Reactivity Of Ketonylgold(III) Complexes – Crystal And Molecular-Structure Of Sp-4-4- Au(2-C6H4N2Ph)(CH2COC6H2(OMe)3-3,4,5)Cl(PPh3) And Sp-4-4- Au(2-C6H4N2Ph)(CH2COMe)Cl(PPh3)

Vicente, J.; Bermúdez, M. D.; Carrillo, M. P.; Jones, P. G. J. Organomet. Chem. 1993, 456, 305.

http://dx.doi.org/10.1016/0022-328x(93)80441-d

 

Synthesis Of Au33+, Au2Ag3+, and Au2Cu3+ Loose Clusters

Vicente, J.; Chicote, M. T.; Lagunas, M. C. Inorg. Chem. 1993, 32, 3748.

http://dx.doi.org/10.1021/ic00069a033

 

Synthesis And Characterization Of Ag(Ch(PPh3)C(O)CH3))2 NO3 – A Multitechnique Experiment In Organometallic Chemistry

Vicente, J.; Chicote, M. T.; Saura-Llamas, I. Journal of Chemical Education 1993, 70, 163.

 

C-F Bond-Cleavage In C6f5x Arenes By Carbonyl-Stabilized Phosphorus Ylides – Synthesis Of Ph3P=C(C6F4X-4)R (X = CN Or NO2) – Crystal And Molecular-Structure Of Ph3P=C(C6F4CN-4)CO2Et

Vicente, J.; Chicote, M. T.; Fernández-Baeza, J.; Fernández-Baeza, A.; Jones, P. G. J. Am. Chem. Soc. 1993, 115, 794.

http://dx.doi.org/10.1021/ja00055a064

 

Some Attempts To Prepare Chelating Nitrophenylpalladium(II) Complexes – Synthesis Of Covalent Arylpalladium(II) Perchlorate Complexes – Crystal And Molecular-Structure Of Catena-trans-(Pd(C6H2(NO2)3-2,4,6)(tht)2(H2O) ClO4)n (tht = Tetrahydrothiophene)

Vicente, J.; Arcas, A.; Borrachero, M. V.; Molins, E.; Miravitlles, C. J. Organomet. Chem. 1992, 441, 487.

http://dx.doi.org/10.1016/0022-328x(92)80180-6

 

Synthesis And Properties Of O-Formylaryl Complexes Of Palladium(II) – Examples Of Organometallic Reactions Of Water-Soluble Arylpalladium(II) Complexes – Unusual Palladium-Assisted Rearrangement Of HC(O)C6H2(OMe)3-3,4,5 to HC(O)C6H2(OMe)3-2,3,4 – X-Ray Structure Of Pd(C6H(CHO)-6-(OMe)3-2,3,4)Cl(bpy)

Vicente, J.; Abad, J. A.; Jones, P. G. Organometallics 1992, 11, 3512.

http://dx.doi.org/10.1021/om00059a013

 

Palladium-Assisted Formation Of Carbon-Carbon Bonds – Stoichiometric Synthesis Of Indenols And Indenones – Catalytic Synthesis Of An Indenol

Vicente, J.; Abad, J. A.; Gil-Rubio, J. J. Organomet. Chem. 1992, 436, C9.

http://dx.doi.org/10.1016/0022-328x(92)85036-v

 

Non-Arylic Diorganothallium Derivatives Obtained By Metalation – Synthesis And Isolation Of The 1st Diketonylthallium(III) Complexes

Vicente, J.; Abad, J. A.; Cara, G.; Gutiérrez-Jugo, J. F. J. Chem. Soc., Dalton Trans. 1992, 2481.

http://dx.doi.org/10.1039/dt9920002481

 

Mercuriation Of 3,4,5-Trimethoxybenzoic Acid – Synthesis Of Derivatives Of The Mercuriation Product And Crystal And Molecular-Structure Of PPh3(CH2Ph) Hgcl(C6H(CO2)-6-(OMe)3-2,3,4)

Vicente, J.; Abad, J. A.; Sandoval, A.; Jones, P. G. J. Organomet. Chem. 1992, 434, 1.

http://dx.doi.org/10.1016/0022-328x(92)83347-k

 

Carbon Hydrogen Activation Of Ketones By 2-Phenylazo-Phenylgold(III) Complexes To Give Ketonylgold(IIII) Complexes

Vicente, J.; Bermúdez, M. D.; Carrillo, M. P.; Jones, P. G. J. Chem. Soc., Dalton Trans. 1992, 1975.

http://dx.doi.org/10.1039/dt9920001975

 

A Facile, Novel Way To Prepare Anionic, Neutral And Cationic Gold(I) Complexes

Vicente, J.; Chicote, M. T.; Saura-Llamas, I.; Lagunas, M. C. J. Chem. Soc., Chem. Commun. 1992, 915.

http://dx.doi.org/10.1039/c39920000915

 

Synthesis Of The 1st Hydroxomonaryltin(IV) Complexes – Crystal And Molecular-Structure Of (Sn C6H3(N=NH6H4-Me-4′)-2,Me-5 Cl2(Mu-OH))2

Vicente, J.; Chicote, M. T.; Ramírez de Arellano, M. C.; Jones, P. G. J. Chem. Soc., Dalton Trans. 1992, 1839.

http://dx.doi.org/10.1039/dt9920001839

 

A New Class Of Au(I)2Ag(I) Cluster

Vicente, J.; Chicote, M. T.; Lagunas, M. C.; Jones, P. G. J. Chem. Soc., Chem. Commun. 1991, 1730.

http://dx.doi.org/10.1039/c39910001730

 

Anionic (Nitrophenyl)Palladium(II) Carbonyls – Crystal-Structure Of cis-PPh3(CH2Ph) Pd(C6H3Me-2,NO2-6)Cl2(CO)

Vicente, J.; Arcas, A.; Borrachero, M. V.; Tiripicchio, A.; Camellini, M. T. Organometallics 1991, 10, 3873.

http://dx.doi.org/10.1021/om00057a017

 

Synthesis And Structural Characterization Of Gold-(I), Gold-(III) And Silver(I) Complexes Of The Ylide Ligand Ph3p=CHC(O)NMe2 – Crystal-Structure Of (AuPPh3)2(Mu-C(PPh3)C(O)NMe2) ClO4

Vicente, J.; Chicote, M. T.; Lagunas, M. C.; Jones, P. G. J. Chem. Soc., Dalton Trans. 1991, 2579.

http://dx.doi.org/10.1039/dt9910002579

 

Platinum-Assisted Addition Of Carbonyl-Stabilized Phosphorus Ylides To Benzonitrile To Give Iminophosphorane Complexes Of Platinum(II) – Crystal and Molecular-Structure Of Trans- PtCl2(E-N(=PPh3)C(Ph)=CHCO2Et)(NCPh)·1/2Me2CO

Vicente, J.; Chicote, M. T.; Fernández-Baeza, J.; Lahoz, F. J.; López, J. A. Inorg. Chem. 1991, 30, 3617.

http://dx.doi.org/10.1021/ic00019a009

 

Gold In Organic-Synthesis – Preparation Of Symmetrical And Unsymmetrical Biaryls Via C-C Coupling From Cis-Diarylgold(Iii) Complexes

Vicente, J.; Bermúdez, M. D.; Escribano, J. Organometallics 1991, 10, 3380.

http://dx.doi.org/10.1021/om00055a063

 

Palladium-Assisted Rearrangement Of HC(O)C6H2(OMe)3-3,4,5 to HC(O)C6H2(OMe)3-2,3,4 – X-Ray Structures Of PdR(PPh3)(Bipy) (CF3SO3) R = C6H(CHO)-6,(OMe)3-2,3,4 And C6H(CHO)-2,(OMe)3-3,4,5-Bipy = 2,2′-Bipyridyl

Vicente, J.; Abad, J. A.; Stiakaki, M. A.; Jones, P. G. J. Chem. Soc., Chem. Commun. 1991, 137.

http://dx.doi.org/10.1039/c39910000137